On the chances and challenges of combining electron-collecting nPOLO and hole-collecting Al-p⁺ contacts in highly efficient p-type c-Si solar cells

authored by

Robby Peibst, Felix Haase, Byungsul Min, Christina Hollemann, Till Brendemühl, Karsten Bothe, Rolf Brendel

Abstract

ISFH is following a distinct cell development roadmap, which comprises—as a short-term concept—the combination of an n-type doped electron-collecting poly-Si on oxide (POLO) junction with an Al-alloyed p⁺ junction for hole collection. This combination can be integrated either in front- and back-contacted back junction cells (POLO-BJ) or in interdigitated back-contacted cells (POLO-IBC). Here, we present recent progress with these two cell concepts. We report on a certified M2-sized 22.9% efficient POLO-BJ cell with a temperature coefficient TC_η of only −(0.3 ± 0.02) %_rel/K and a certified 23.7% (4 cm² d.a.) efficient POLO-IBC cell. We discuss various specific conceptual aspects of this technology and present a simulation-based sensitivity analysis for quantities related to the quality of the hole-collecting alloyed Al-p⁺ junction which are subject to continuous improvement and thus hard to predict exactly. We report that the measured pseudo fill factor values decrease more due to metallization than would be expected from recombination in the metallized regions with an ideality factor of one only. The gap to pseudo fill factor values that are theoretically achievable at the respective open-circuit voltages is 1.1%_abs (Ga-doped wafer) for POLO-IBC and 1.4%_abs (B-doped wafer) to 2%_abs (Ga-doped wafer) for POLO-BJ. With an embedded blocking layer for Ag crystallites in the poly-Si, we present a concept to reduce this gap.

Organisation(s)

Institute of Electronic Materials and Devices
Solar Energy Section

External Organisation(s)

Institute for Solar Energy Research (ISFH)

Type

Article

Journal

Progress in Photovoltaics: Research and Applications

Volume

31

Pages

327-340

No. of pages

14

ISSN

1062-7995

Publication date

01.03.2023

Publication status

Published

Peer reviewed

Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials, Renewable Energy, Sustainability and the Environment, Condensed Matter Physics, Electrical and Electronic Engineering

Sustainable Development Goals

SDG 7 - Affordable and Clean Energy

Electronic version(s)

https://doi.org/10.1002/pip.3545 (Access: Open)