Pinhole density and contact resistivity of carrier selective junctions with polycrystalline silicon on oxide

authored by
T. F. Wietler, D. Tetzlaff, J. Krügener, M. Rienäcker, F. Haase, Y. Larionova, R. Brendel, R. Peibst
Abstract

In the pursuit of ever higher conversion efficiencies for silicon photovoltaic cells, polycrystalline silicon (poly-Si) layers on thin silicon oxide films were shown to form excellent carrier-selective junctions on crystalline silicon substrates. Investigating the pinhole formation that is induced in the thermal processing of the poly-Si on oxide (POLO) junctions is essential for optimizing their electronic performance. We observe the pinholes in the oxide layer by selective etching of the underlying crystalline silicon. The originally nm-sized pinholes are thus readily detected using simple optical and scanning electron microscopy. The resulting pinhole densities are in the range of 6.6 × 106 cm-2 to 1.6 × 108 cm-2 for POLO junctions with selectivities close to S10 = 16, i.e., saturation current density J0c below 10 fA/cm2 and contact resistivity ρc below 10 mΩcm2. The measured pinhole densities agree with values deduced by a pinhole-mediated current transport model. Thus, we conclude pinhole-mediated current transport to be the dominating transport mechanism in the POLO junctions investigated here.

Organisation(s)
Institute of Electronic Materials and Devices
Laboratory of Nano and Quantum Engineering
Institute of Solid State Physics
External Organisation(s)
Institute for Solar Energy Research (ISFH)
Type
Article
Journal
Applied physics letters
Volume
110
ISSN
0003-6951
Publication date
19.06.2017
Publication status
Published
Peer reviewed
Yes
ASJC Scopus subject areas
Physics and Astronomy (miscellaneous)
Sustainable Development Goals
SDG 7 - Affordable and Clean Energy
Electronic version(s)
https://doi.org/10.1063/1.4986924 (Access: Closed)