Impurity-related limitations of next-generation industrial silicon solar cells

authored by
Jan Schmidt, Bianca Lim, Dominic Walter, Karsten Bothe, Sebastian Gatz, Thorsten Dullweber, Pietro P. Altermatt
Abstract

We apply highly predictive 2-D device simulation to assess the impact of various impurities on the performance of next-generation industrial silicon solar cells. We show that the light-induced boron-oxygen recombination center limits the efficiency to 19.2% on standard Czochralski-grown silicon material. Curing by illumination at elevated temperature is shown to increase the efficiency limit by $+$1.5% absolute to 20.7%. In the second part of this paper, we examine the impact of the most important metallic impurities on the cell efficiency for p-and n-type cells. It is widely believed that solar cells on n-type silicon are less sensitive to metallic impurities. We show that this statement is not generally valid as it is merely based on the properties of Fe but does not account for the properties of Co, Cr, and Ni.

External Organisation(s)
Institute for Solar Energy Research (ISFH)
Type
Article
Journal
IEEE journal of photovoltaics
Volume
3
Pages
114-118
No. of pages
5
ISSN
2156-3381
Publication date
2013
Publication status
Published
Peer reviewed
Yes
ASJC Scopus subject areas
Electronic, Optical and Magnetic Materials, Condensed Matter Physics, Electrical and Electronic Engineering
Sustainable Development Goals
SDG 7 - Affordable and Clean Energy
Electronic version(s)
https://doi.org/10.1109/JPHOTOV.2012.2210030 (Access: Unknown)