Utilization of sodium waterglass from sugar cane bagasse ash as a new alternative hardener for producing metakaolin-based geopolymer cement

verfasst von

Hervé Kouamo Tchakouté, Claus Henning Rüscher, Malte Hinsch, Local Materials Authority, Local Materials Authority, Cristina Leonelli

Abstract

Sugar cane bagasse ash from SOSUCAM company in Cameroon was used to synthesize sodium waterglass as a new alternative hardener. The new hardener was used to prepare metakaolin-based geopolymer cements. The compressive strength of the resulting geopolymer cement cured at room temperature for 28 days was 32.9 MPa. Samples soaked for 28 days in water in parallel experiments revealed a strength of 31.4 MPa. This shows that exposure of water does not lead to any weakening. The value of water absorption was 7.1% in the water-soaked cements, indicating the presence of fewer pores and voids than in the dry cements. However, in SEM micrographs, the microstructure of geopolymer cement appears rather homogeneous and compact without any change by water soaking. It can thus be concluded that sodium waterglass from sugar cane bagasse ash can be used as an alternative hardener or reactive ingredient for producing geopolymer cement with a high degree of cross-linking geopolymer framework. The use of this low-value silica-rich waste for producing sodium waterglass results in environmental benefits including a significant reduction of CO₂ emission and energy consumption compared to the production of commercial sodium waterglass.

Organisationseinheit(en)

Institut für Mineralogie

Externe Organisation(en)

University of Yaounde I
University of Modena and Reggio Emilia
Local Material Promotion Authority (MIPROMALO)

Typ

Artikel

Journal

Chemie der Erde

Band

77

Seiten

257-266

Anzahl der Seiten

10

ISSN

0009-2819

Publikationsdatum

24.04.2017

Publikationsstatus

Veröffentlicht

Peer-reviewed

Ja

ASJC Scopus Sachgebiete

Geophysik, Geochemie und Petrologie

Ziele für nachhaltige Entwicklung

SDG 7 – Erschwingliche und saubere Energie

Elektronische Version(en)

https://doi.org/10.1016/j.chemer.2017.04.003 (Zugang: Geschlossen)