Modeling a thermocell with proton exchange membrane and hydrogen electrodes
- verfasst von
- T. Marquardt, G. Valadez Huerta, S. Kabelac
- Abstract
Direct conversion of thermal energy to electric energy with thermoelectric generators is an attractive technique to recover low-temperature heat. Thermoelectric generators based on galvanic cells (thermocells) provide promising results with respect to the Seebeck coefficient. In this study, based on the theory of non-equilibrium thermodynamics, we simulated a thermocell with hydrogen gas electrodes and a proton exchange membrane. We calculated a maximum power density of 1461 mW/m2 and a thermal efficiency of 2% relative to the Carnot efficiency for a cell operating with the same gas composition at both the anode and the cathode, but fully saturated at the anode. We predict a Seebeck coefficient in the range of 0.7–1.8 mV/K, higher than those of classical thermoelectric generators. The thermocell presented here provides promising values regarding the Seebeck coefficient.
- Organisationseinheit(en)
-
Institut für Thermodynamik
- Typ
- Artikel
- Journal
- International Journal of Hydrogen Energy
- Band
- 43
- Seiten
- 19841-19850
- Anzahl der Seiten
- 10
- ISSN
- 0360-3199
- Publikationsdatum
- 25.10.2018
- Publikationsstatus
- Veröffentlicht
- Peer-reviewed
- Ja
- ASJC Scopus Sachgebiete
- Erneuerbare Energien, Nachhaltigkeit und Umwelt, Feuerungstechnik, Physik der kondensierten Materie, Energieanlagenbau und Kraftwerkstechnik
- Ziele für nachhaltige Entwicklung
- SDG 7 – Erschwingliche und saubere Energie
- Elektronische Version(en)
-
https://doi.org/10.1016/j.ijhydene.2018.09.007 (Zugang:
Geschlossen)