Bi-Based Metal Halide Perovskites and Their Photocatalytic Properties

A Review

verfasst von
Yan Jie Li, Ben Hong Mu, Hong Bin Li, Shuang Chao Tang, Jie Tian, Yu Li, Zhuo Yu Ji, Yan Jie Wang, Tao He, Alexei V. Emeline, Detlef W. Bahnemann, Jia Hong Pan
Abstract

Semiconductor photocatalysis is a sustainable technology to address environmental pollution problems by efficiently utilizing solar energy. Developing efficient photocatalysts is particularly important. Recently, metal halide perovskites, especially lead halide perovskites (LHPs), have garnered widespread interest in photocatalytic fields due to their unique optoelectronic properties. However, the high toxicity of elemental lead has become a significant obstacle restricting the practical application of LHPs. In response, bismuth halide perovskites (BHPs) have emerged as a promising alternative. This review summarizes recent advances in this exciting area. First, we examine the wet-chemical synthesis methods for various BHPs. The physicochemical properties of BHPs are then discussed, with special emphasis on their stability. Methods to enhance stability, including composition engineering, surface engineering, and packaging engineering, are described. Emerging applications of BHPs in photocatalytic hydrogen production (H2), carbon dioxide (CO2) reduction, oxynitride (NOx) oxidation, organic synthesis and pollutant dye degradation are also reviewed. Finally, the challenges faced by BHPs and future research directions are analyzed and prospected.

Organisationseinheit(en)
Institut für Technische Chemie
Externe Organisation(en)
North China Electric Power University (NCEPU)
Guangxi University
Chinese Academy of Sciences (CAS)
Graduate University of Chinese Academy of Sciences
Staatliche Universität Sankt Petersburg
Typ
Übersichtsarbeit
Journal
Energy and Fuels
Band
39
Seiten
2986-3007
Anzahl der Seiten
22
ISSN
0887-0624
Publikationsdatum
13.02.2025
Publikationsstatus
Veröffentlicht
Peer-reviewed
Ja
ASJC Scopus Sachgebiete
Allgemeine chemische Verfahrenstechnik, Feuerungstechnik, Energieanlagenbau und Kraftwerkstechnik
Ziele für nachhaltige Entwicklung
SDG 7 – Erschwingliche und saubere Energie, SDG 12 – Verantwortungsvoller Konsum und Produktion
Elektronische Version(en)
https://doi.org/10.1021/acs.energyfuels.4c06208 (Zugang: Geschlossen)